Sunday, 29 November 2015

microwave heating problem

I’m heating up my food using a microwave. I’m heating some sweet potatoes and I figured since I mash it with milk later, I can immerse them in milk during the heating. But, unlike the sweet potato alone which heats up really fast, the milk + sweet potato doesn’t heat up that fast… That got me thinking… Why?
Here’s my hypothesis. The increase in temperature is associated with increase in the AVERAGE thermal energy. In thermodynamics, this is an intensive property (does not scale with size). As opposed to the average, think about heat which is a measure of thermal energy. As the total amount increases, assuming the same temperature, the total heat increases. This is an extensive propery.
Now, let’s think about how much heat we need to put in to change the temperature. For example, we know (from experience) that metal heats up really fast. Metal has low heat capacity compared to say water. (We shouldn’t confuse between heat capacity and thermal conductivity. Metals have high thermal conductivity which means the heat propagates faster. It doesn’t say how much energy is needed to raise its temperature.)
Now, I think the answer is somewhat simple… The sweet potato has lower heat capacity and thus needs less energy to heat it. Assuming that the heat input is constant, this means that the temperature (how I measure “hotness”) is higher faster. Adding milk is like adding more stuff but also stuff with high heat capacity… you need more energy to change its temperature by the same amount.

But then one question remains… is the heat input really constant? I know that the microwave is operating at the same power (energy per time), but it does not tell me that the energy is used up as heat… Microwave works by injecting microwave radiation into the system which should absorb this radiation. Molecularly, the species that absorbs the radiation enters a higher energy vibrational mode which is translated as heat. But if you have more radiation absorbing species, conversion to thermal energy might be greater. I don’t think this plays a big role in my milk + sweet potato case… but I do wonder for other food matter… I know that water tends to absorb this radiation or at least a lot of posts online talk about how water absorbs this energy… but I’ll need to think more about what happens to almost completely dry materials.